Irdium complexes

Johnson Matthey offers a selection of iridium complexes for various applications. JM’s iridium complex products can be combined with a variety of ligand classes such as phosphines, cyclopentadienyls, NHCs and polypyridyl ligands to form active Ir catalysts for a variety of applications. Example applications include asymmetric hydrogenation (1), asymmetric C-C and C-N bond formation, cyclometallation, direct C-H borylation (2) and photoredox catalysis (3). 

References: 

1. 1. Kim, A. N. and Stoltz, B.M.  ACS Catalysis 2020 10 (23), 13834-13851. 
2. 2. (a) Slack, E.D.  and Colacot, T.J. Organic Letters 2021 23 (5), 1561-1565; (b) D’Angelo, K.A.;        La, C.; Kotecki, B.;Wilson, J.W.; Karmel, C.; Swiatowiec, R.; Tu, N. P.; Shekhar, S. and           
3.     Hartwig,F.J.  J. Am. Chem. Soc. 2024 146 (47), 32717-32729 
4. 3. Shaw, M.H.; Twilton, J. and MacMillan, D. W. C. J. Org. Chem. 2016 81 (16), 6898-6926