Pd-175

[tBuBrettPhos Pd(allyl)]OTf

CAS Number: 1798782-15-6

Pi-allyl catalyst highly active across a range of challenging cross-couplings including C-N couplings with substrates such as amides and ammonia. Undergoes rapid activation and accommodates the extremely bulky tBuBrettPhos ligand, as well as avoiding the formation of carbazole that has been shown to suppress reactivity in some coupling reactions.
 
specifications

Description:
[tBuBrettPhos Pd(allyl)]OTf
 

Formula:
C35H54F3O5PPdS
 

Molecular Weight:
781.26
 

Metal:
Pd
 

Metal %:
13.62%
 

Long Description:
allyl(2-di-tert-butylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)palladium(II) triflate
 

References:

 

Bourriquen, F.; Bruneau‐Voisine, A.; Jeandin, A.; Stihle, E.; Fantasia, S. Chem. Eur. J. 2019, 25, 9006

DeAngelis, A. J.; Gildner, P. G.; Chow, R.; Colacot, T. J. J. Org. Chem. 2015, 80, 6794

 

 

 

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