Hydroformylation-Catalysts-Rh-42-Rh-43-and-Rh-50
Hydroformylation catalysts Rh-42, Rh-43 (ROPAC) and Rh-50
Our rhodium hydroformylation catalysts are air stable, contain no halide and have good solubility in organic solvents. They are normally used with ligands such as triphenylphosphine.
ROPAC has a higher rhodium content than Rh-42 and has been used for hydroformylation since the development of the low pressure oxo process in the 1970’s.
Rh-50 is more hazardous than ROPAC and has a significant vapour pressure. It should be handled with appropriate precautions.
Product | Chemical formula | Chemical structure | Product codes | CAS number | Rhodium content | Colour |
|
Rh-42 | (CO)H(PPh3)3Rh | ![]() |
UK: 209042 US: C3021 |
17185-29-4 | 10.0-11.4 %w/w |
Yellow
|
|
Rh-43, ROPAC | Rh(CO)(PPh3)(acac) | ![]() |
UK: 207000 | 25470-96-6 | 19.3 – 21.2 %w/w |
Yellow
|
|
Rh-50, rhodium coacac | Rh(acetylacetonate)(CO)2 | ![]() |
UK: 209050 US: C3022 |
14874-82-9 | 38.5 – 40.0 % w/w |
Red/green (dichroic)
|
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