Nickel complexes

In recent years the advancement of base metal catalysis, particularly nickel, in various industrial applications has received significant attention in scientific literature (1). A major benefit of homogeneous nickel catalysis is that it enables the use of novel chemistries and substrates in synthetic applications that can’t be achieved with stoichiometric reagents or other catalytic technologies.

Johnson Matthey now offers a selection of versatile nickel precursors and precatalysts for a variety of cross coupling reactions, including Suzuki-Miyaura couplings, Miyaura borylation, and photoredox applications.

Reference:

1. (a) Org. Process Res. Dev. 2023, 27, 11, 1913-1930; (b) Org. Process Res. Dev. 2021, 25, 7, 1471-1495; (c) Org. Process Res. Dev. 2022, 26, 8, 2281-2310; (d) Org. Process Res. Dev. 2022, 26, 1, 14-42; (e) Org. Process Res. Dev. 2021, 25, 8, 1802-1815, (f) Org. Process Res. Dev. 2020, 24, 6, 909-91

NiCl₂(dppe)
Product number: Ni-103
CAS number: 14647-23-5
Mol weight: 528.02
Reaction type: Suzuki coupling, Miyaura borylation
NiCl₂(dppf)
Product number: Ni-107
CAS number: 67292-34-6
Mol weight: 683.98
Reaction type: Suzuki coupling, Miyaura borylation
NiCl₂(PCy₃)₂
Product number: Ni-114
CAS number: 19999-87-2
Mol weight: 690.46
Reaction type: Suzuki coupling, Miyaura borylation
NiCl₂(dppp)
Product number: Ni-126
CAS number: 15629-92-2
Mol weight: 542.05
Reaction type: Suzuki coupling, Miyaura borylation
NiCl₂(dcypf)
Product number: Ni-127
CAS number: 917511-89-8
Mol weight: 708.18
Reaction type: Suzuki coupling, Miyaura borylation
NiCl₂(PPh₃)₂
Product number: Ni-128
CAS number: 14264-16-5
Mol weight: 654.17
Reaction type: Suzuki coupling, Miyaura borylation
Ni(COD)₂
Product number: Ni-129
CAS number: 1295-35-8
Mol weight: 275.06
Reaction type: Suzuki coupling, Miyaura borylation, photocatalysis
[(TMEDA)Ni(o-tolyl)Cl]
Product number: Ni-130
CAS number: 1702744-45-3
Mol weight: 301.48
Reaction type: Suzuki coupling, Miyaura borylation, photocatalysis
Ni(COD)(DQ)
Product number: Ni-131
CAS number: 140759-64-6
Mol weight: 331.08
Reaction type: Suzuki coupling, Miyaura borylation, photocatalysis         
NiCl₂(dtbbpy)
Product number: Ni-133
CAS number: 1034901-50-2
Mol weight: 398

Reaction type: photocatalysis    

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