Pd-213

Catalogue Number: Pd-213

CAS Number: 166445-62-1
 


specifications

Description:
{Pd(µ-I) [P(tBu)3]}2

Formula:
C24H54P2I2Pd2

Molecular Weight:
871.29

Metal:
Pd

Metal %:
24.43%

Long Description:
di-µ-iodo-bis(tri-tert-butylphosphine)dipalladium(I)

Our optimised cross-coupling catalyst provides various advantages to your reaction: 

  • Air and moisture stable Pd(I) precatalyst
  • Safe source of pyrophoric, electron-rich and bulky PtBu3 ligand
  • Complements PtBu3-containing catalysts, Pd-162 and Pd-168
  • Efficient precatalyst for challenging cross-coupling reactions (e.g. chemoselective Csp2-Csp2, Csp2-Csp3, C-S, C-SCF3 and C-SeCF3 bond formation)

 

Selected references:

Franziska Schoenebeck and co-workers:

Angew. Chem. Int. Ed. 2018, 57, 12573; Angew. Chem. Int. Ed. 2018, 57, 12425; Angew. Chem. Int. Ed. 2017, 56, 7078; Angew. Chem. Int. Ed. 2017, 56, 1581; Synthesis 2017, 49, 115; Organometallics 2015, 34, 5191; Angew. Chem. Int. Ed2015, 54, 10322; Angew. Chem. Int. Ed. 2015, 54, 6809. 

 

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Connie Schlegel