Suzuki coupling catalysts

Carbon-carbon bond forming reactions are essential to the discovery and manufacturing of small molecules across the chemical industry. The Suzuki-Miyaura (SM) coupling has become the most widely used of these Pd-catalysed carbon-carbon bond forming reactions due to the stability, reactivity and tunability of boronic acid derivatives when compared to other C-C coupling methodologies. A wide variety of Suzuki coupling palladium catalyst products or Ni-based catalyst systems and phosphine ligands can be used, enabling chemists to construct a very broad range of small molecules with this transformation.  

Johnson Matthey offers an extensive portfolio of phosphine ligated precatalysts designed for a full range of Suzuki coupling reactions. 

Palladium coupling PdL₂X₂

PdCl₂(PPh₃)₂

Product: Pd-100

PdCl₂(dppf)·CH₂Cl₂

Product: Pd-106

PdCl₂(Cy₃P)₂

Product: Pd-114

PdCl₂ DPEPhos

Product: Pd-117

PdCl₂(dtbpf)

Product: Pd-118

PdCl₂(dppp)

Product: Pd-126

PdCl₂ (Amphos)₂

Product: Pd-132

PdCl₂ (XantPhos)

Product: Pd-134

PdCl₂ [P(tBu)(Cy)₂]₂

Product: Pd-166

Pi-allyl palladium complexes

XantPhos Pd(allyl)Cl

Product: Pd-177

XPhos Pd(crotyl)Cl

Product: Pd-170

RuPhos Pd(crotyl)Cl

Product: Pd-17

SPhos Pd(crotyl)Cl

Product: Pd-172

CyJohnPhos Pd(crotyl)Cl

Product: Pd-188

Buchwald precatalysts

XPhos Pd G2

Product: BPC-201

SPhos Pd G2

Product: BPC-203 

RuPhos Pd G2

Product: BPC-206 

PCy₃ Pd G2

Product #: Pd-168

XantPhos Pd G2

Product: Pd-179

APhos Pd G2

Product: Pd-183

PdCl2(dppf)·CH2Cl2

Product: Pd-185

XPhos Pd G3

Product: BPC-301 

tBuXPhos Pd G3

Product: BPC-302

SPhos Pd G3

Product: BPC-303

RuPhos Pd G3

Product: BPC-306

P(Ad)₂(nBu) Pd G3

Product: BPC-307

APhos Pd G3

Product: Pd-184 

XantPhos Pd G3

Product: Pd-187

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